Pirovano was a priest. He studied philosophy and theology for the priesthood at the Compagnia di San Paolo brotherhood and was ordained in Rome in San Giovanni in Laterano on 20 December 1952. He earned a degree in theology from the Gregorian University, and asked to be a priest in the Diocese of Rome. He was a pastor, scholar, theologian, friend and collaborator of Don Angelo Tosato, Father Enrico di Rovasenda, Roberto Ruffilli, Don Antonio Acerbi, Francesco Traniello and Pietro Scoppola.

The collection includes 776 SBN catalogued monographic publications.

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